Target Spider-Man / Doctor Octopus: Greatest Battles #1

Otto Octavius is caught in an explosion during an experiment and the metal arms he is wearing are fused to his body. Jameson sends Peter out to get pics of this Doc Ock kook and Spider-Man battles him for the first time. And loses. Despondent over the loss, Peter is inspired by a speech by the Human Torch and finds the courage to battle Doc Ock again and defeat him.